Galvanic cell, Nernst equation, and concentration cell visualization.
Cell Potential (Standard):
E°cell = E°cathode - E°anode
Spontaneous when E°cell > 0
Nernst Equation (at 298 K):
Ecell = E°cell - (RT/nF) ln Q
Ecell = E°cell - (0.0592/n) log Q
Reaction Quotient:
Q = [products]^coeff / [reactants]^coeff
Gibbs Free Energy:
ΔG = -nFEcell
ΔG° = -nFE°cell
Spontaneous when ΔG < 0
Concentration Cell:
Ecell = -(RT/nF) ln([dilute]/[concentrated])
Same metal, different concentrations